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91.
A water circulation system with the almost same element composition and socket type was adopted in coral Acropora culture under different seawater pH value conditions and the data of the relationship between boron isotopic compositions of coral and seawater pH value by thermoelectric ionization mass spectrometer were obtained. According to the correlations between αcarb-3 of coral and the pH value of cultured seawater, αcarb-3 was not a constant but related to pH value, indicating that B(OH)3 also incorporated carbonate. Therefore, the theoretical formula could not be used to calculate the seawater pH value from the δ11Bcarb value of the measured marine biological carbonate. The empirical equations obtained experimentally would be an alternative method to calculate the seawater pH value. In addition, the mixed precipitation of CaCO3 and Mg(OH)2 was found in aquaculture tanks with high pH value, and the δ11B of the solid was significantly higher than that of cultured seawater. The result indicated that the presence of Mg(OH)2 had a significant effect on the boron isotope fractionation, which deserved our attention. 相似文献
92.
A new Schiff base hydrazone (Z)‐2‐(2‐aminothiazol‐4‐yl)‐N′‐(2‐hydroxy‐3‐methoxybenzylidene) acetohydrazide (H2L) and its chelates [VO (HL)2]·5H2O, [Cu (HL)Cl(H2O)]·2H2O and [Fe(L)Cl(H2O)2]·3H2O have been isolated and characterized using different physico‐chemical methods, for example infrared (IR), electron paramagnetic resonance (EPR), thermogravimetric analysis and DTG in the solid state, and 1H‐NMR, 13C‐NMR and UV in solution. Magnetic and UV–visible measurements proposed that the coordination environments are square pyramidal, tetrahedral and octahedral geometries for oxovanadium (IV), Cu (II) and Fe (III), respectively. The ligand acts as mono‐negative NO towards oxovanadium (IV) and Cu (II) ions, and bi‐negative ONO for Fe (III) ion. The geometries of the ligand and its complexes were performed using Gaussian 9 program with density functional theory. The EPR spectral data of oxovanadium (IV) and Cu (II) chelates confirmed the mentioned geometries. The molecular modeling was done, and illustrated bond lengths, bond angles, molecular electrostatic potential, Mulliken atomic charges and chemical reactivity for the inspected compounds. Theoretical IR and 1H‐NMR of the free ligand were calculated. Furthermore, thermodynamic and kinetic parameters for thermal decomposition steps were studied. Docking study of H2L was applied against the proteins of both bacterial strains Staphylococcus aureus and Escherichia coli, as well as the protein of xanthine oxidase as antioxidant agent by Schrödinger suite program utilizing XP glide protocol. Furthermore, antimicrobial, antioxidant and DNA‐binding activities of the compounds have been carried out. 相似文献
93.
Areeba Ikram 《Journal of Difference Equations and Applications》2019,25(6):757-775
ABSTRACTWe will establish uniqueness of solutions to boundary value problems involving the nabla Caputo fractional difference under two-point boundary conditions and give an explicit expression for the Green's functions for these problems. Using the Green's functions for specific cases of these boundary value problems, we will then develop Lyapunov inequalities for certain nabla Caputo BVPs. 相似文献
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95.
By means of ab initio calculation based on density-functional theory (DFT), we have investigated the electronic and optical properties of single layer MoSe2 under chemical doping by various groups, such as ?H, ?OH, ?NH2 and ?CH3. This work is generalized for all polymorph 1H, 1T, 1T′ and the new investigated phase 1T″. We found that all those functional groups (FG) bonded covalently to the chalcogen atom (Se). The evaluation of adsorption energy shows that the hydrogen atom binds more strongly than other functional groups in particular with the T phase. Furthermore, the attachment of functional groups to T-MoSe2 leads to dramatic changes to the structure stability and the optoelectronic properties of the material by tuning its band gap from metallic to a semiconductor. Also, we found that the band gap is strongly depending on the type and the densities of dopants. 相似文献
96.
97.
98.
Thomas Mikosch Mohsen Rezapour Olivier Wintenberger 《Stochastic Processes and their Applications》2019,129(11):4638-4662
In this paper we consider a stochastic model of perpetuity-type. In contrast to the classical affine perpetuity model of Kesten (1973) and Goldie (1991) all discount factors in the model are mutually independent. We prove that the tails of the distribution of this model are regularly varying both in the univariate and multivariate cases. Due to the additional randomness in the model the tails are not pure power laws as in the Kesten–Goldie setting but involve a logarithmic term. 相似文献
99.
Wen‐ming He 《Numerical Methods for Partial Differential Equations》2019,35(6):2044-2055
In this article, we will discuss the local ultraconvergence of high‐degree finite element method based on a rectangular partition for the second‐degree elliptic problem with constant coefficients in Ω ? ?2 , u( y ) = 0 on ?Ω . Based on suitable regularity, ultraconvergence of the displacement of the extrapolated kth (k ≥ 3) degree finite element solution has been obtained by an extrapolation technique. Finally, numerical experiments are applied to demonstrate our theoretical findings. 相似文献
100.
Tracy E. Dobie 《Mathematical Thinking and Learning》2019,21(1):28-53
This research explores how adolescents conceptualize the usefulness of mathematics. Integrating sociocultural theory with the study of utility value, this study uses open-ended survey items and interview tasks to examine conceptions of usefulness among a group of predominantly Latinx middle school students. Findings reveal that students primarily conceptualized the usefulness of mathematics in two ways. First, students considered the applicability of mathematics content, focusing on applications of mathematics in everyday life and future jobs/careers. Second, students considered the usefulness of features of the learning experience, such as the form of interaction and structure of the activity. Both conceptions are compared to existing conceptions of usefulness in the literature, and implications for classroom practice and future research are discussed. 相似文献